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Nickel Cross-Coupling Cascades with α-Heteroatom Radicals to Prepare Sterically Hindered Alcohols and Amines

Organization UNIVERSITY OF WISCONSIN-MADISONLocation MADISON, UNITED STATESPosted 15 Feb 2023Deadline 11 Apr 2025 ⚠️
NIHUS FederalResearch GrantFY2025AcademiaAcidsAcylationAdoptedAlcohol Chemical ClassAlcoholsAminesAmino AcidsAmino AlcoholsAreaBypassCarbonChemicalsComplexCouplingDevelopmentDissociationDrug Synthesis and ChemistryDrugsFree RadicalsFutureGenerationsGoalsH elementHydrogenIn SituIndustryInterceptKetonesLigandsMediatorMedicationMethodologyMethodsMolecular ConfigurationMolecular ConformationMolecular StereochemistryNatural ProductsNi elementNickelOutcome StudyPathway interactionsPharmaceutical AgentPharmaceutical PreparationsPharmaceuticalsPharmacologic SubstancePharmacological SubstanceProcessProductionReactionReagentamineaminoacidaminoalcoholbioactive natural productsconformationconformationalconformational stateconformationallyconformationsdevelopmentaldriving forcedrug candidatedrug developmentdrug discoverydrug synthesisdrug/agentforgingfunctional groupimprovedinterestketalnaturally occurring productnon-natural amino acidsnon-proteinogenic amino acidsnonproteinogenic amino acidsnovelpathwaypharmaceuticalscaffoldscaffoldingunnatural amino acids

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Description preview

Project Summary
The overarching theme of this proposal is to apply robust and reliable reaction mechanisms to improve the

efficiency of forming C–C bonds adjacent to alcohol or amine functionality. Among the most common strategies

to these products is the addition of a Grignard reagent (or other carbon nucleophile) to a ketone or ketimine…

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Nickel Cross-Coupling Cascades with α-Heteroatom Radicals to Prepare Sterically Hindered Alcohols and Amines — UNIVERSIT | Dev Procure